Open the file /etc/hosts.
Add the following entries..
127.0.0.1 chatenabled.mail.google.com //To block Gmail chat
127.0.0.1 talkgadget.google.com //To block iGoogle and orkut chat
127.0.0.1 talk.google.com //To block the Google Talk client
127.0.0.1 talkx.l.google.com //To block the Google Talk client
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